Fe + 4 Hno3 ↠ Fe(No3)3 + No + 2 H2O

     

In the ion-electron method (also called the half-reaction method), the redox equation is separated into two half-equations - one for oxidation và one for reduction. Each of these half-reactions is balanced separately and then combined khổng lồ give the balanced redox equation.

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Step 1. Write down the unbalanced equation ("skeleton equation") of the chemical reaction. All reactants and products must be known. For a better result write the reaction in ionic form.


Step 2. Separate the redox reaction into half-reactions. A redox reaction is nothing but both oxidation và reduction reactions taking place simultaneously.


a) Assign oxidation numbers for each atom in the equation. Oxidation number (also called oxidation state) is a measure of the degree of oxidation of an atom in a substance (see: Rules for assigning oxidation numbers).


b) Identify & write out all redox couples in reaction. Identify which reactants are being oxidized (the oxidation number increases when it reacts) & which are being reduced (the oxidation number goes down).


c) Combine these redox couples into two half-reactions: one for the oxidation, & one for the reduction (see: Divide the redox reaction into two half-reactions).


Step 3. Balance the atoms in each half reaction. A chemical equation must have the same number of atoms of each element on both sides of the equation. địa chỉ cửa hàng appropriate coefficients (stoichiometric coefficients) in front of the chemical formulas. Never change a formula when balancing an equation. Balance each half reaction separately.


a) Balance all other atoms except hydrogen and oxygen. We can use any of the species that appear in the skeleton equations for this purpose. Keep in mind that reactants should be added only to lớn the left side of the equation và products to lớn the right.


b) Balance the oxygen atoms. Check if there are the same numbers of oxygen atoms on the left và right side, if they aren"t equilibrate these atoms by adding water molecules.


c) Balance the hydrogen atoms. Kiểm tra if there are the same numbers of hydrogen atoms on the left and right side, if they aren"t equilibrate these atoms by adding protons (H+).

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Step 4. Balance the charge. To balance the charge, địa chỉ cửa hàng electrons (e-) to lớn the more positive side to lớn equal the less positive side of the half-reaction. It doesn"t matter what the charge is as long as it is the same on both sides.


Step 5. Make electron gain equivalent khổng lồ electron lost. The electrons lost in the oxidation half-reaction must be equal the electrons gained in the reduction half-reaction. To make the two equal, multiply the coefficients of all species by integers producing the lowest common multiple between the half-reactions.


Step 6. địa chỉ cửa hàng the half-reactions together. The two half-reactions can be combined just like two algebraic equations, with the arrow serving as the equals sign. Recombine the two half-reactions by adding all the reactants together on one side và all of the products together on the other side.


Step 7. Simplify the equation. The same species on opposite sides of the arrow can be canceled. Write the equation so that the coefficients are the smallest phối of integers possible.


Finally, always check to see that the equation is balanced. First, verify that the equation contains the same type & number of atoms on both sides of the equation.


Second, verify that the sum of the charges on one side of the equation is equal to lớn the sum of the charges on the other side. It doesn"t matter what the charge is as long as it is the same on both sides.


Since the sum of individual atoms on the left side of the equation matches the sum of the same atoms on the right side, và since the charges on both sides are equal we can write a balanced equation.

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Citing this page:

Generalic, Eni. "Balancing redox reactions by the ion-electron method." EniG. Periodic Table of the Elements. KTF-Split, 25 Jan. 2022. Web. Date of access. .


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